Design and implementation of the detector control system for the BESⅢ drift chamber cosmic ray test

After the construction of the BESⅢ drift chamber, a long period of cosmic rays test is necessary to verify its performance. This also provides a good opportunity to integrate the detector readout electronics and Detector Control System (DCS) into a unified working system. The goal of the DCS is to guarantee reliable physics data quality and the safe operation of the detector. It monitors and controls the HV, gas, VME crates and the nvironmental variables. The upper-level system is mainly developed from LabVIEW and the lower-level system mainly uses MCU and PLC technology. The system is designed to be highly flexible and scalable so that it can be applied to other detectors with little or no change. In the immediate future, it will be integrated into the entire BESⅢ Slow Control System.     

Refraction Light Control by Constructing Output Interface Topography of Metal Waveguide Arrays

We investigate a nanoscale metal waveguide array (MWGA) structure and demonstrate that negative refraction effect exists from the visible to infrared frequency. Our numerical analysis shows that this effect is related to outputinterface of MWGAs. Refraction light would have different directions on the gradient shaped output surface as a result of phase retardation control by waveguide thickness. Finite-difference time-domain analysis shows that more sharp superdiffraction limit imaging can be obtained by constructing convex-like output interface topography.     

Synthesis,Crystal Structure,Fungicidal Activities and Molecular Docking of Acyl Urea Derivatives Containing 2-Chloronicotine Motif

Eighteen new acyl urea derivatives containing 2-chloronicotine moiety were synthesized using2-chloronicotinic acid as starting material via 4 steps conveniently.These 2-chloronicotine acyl urea structures were confirmed by ¹H NMR,¹³C NMR and HRMS.Compound 4r was further confirmed by X-ray diffraction.It crystallizes in the orthorhombic system,space group Pbca with a=7.2960（3）,b=14.8546（6）,c=25.2840（11）?,V=2740.3（2）?³,Z=8,the final R=0.0442 and w R=0.1033 for 4028...     

氧碘化学激光器增益谱线的精细结构及腔内温度

 采用可调谐二极管激光器做探测光源,测量了超音速氧碘化学激光器增益谱线的精细结构,得到了各谱线相对强度的百分比。同时也推得了增益线宽与腔内温度。     

Catalytic Oxidation of Cyclohexene with Molecular Oxygen on Hydrotalcite－like Compounds

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杂多阴离子柱撑水滑石的合成、热稳定性、酸碱性研究

采用水溶液中阴离子直接交换法合成了过渡金属单取代Keggin结构杂多阴离子SiW11M(H2O)O39^6^- (M=Mn^2^+, Fe^2^+, Co^2^+, Ni^2^+, Cu^2^+,Zn^2^+)柱撑水滑石。用元素分析、XRD和IR对产物的组成与结构进行了表征。XRD结果给出柱撑产物的底面间距达1.47nm。DTA结合不同温度下焙烧样品的XRD、IR研究表明, 柱撑水滑石在低于250℃时脱除物理吸附水和层间水; 在400~500℃之间脱除层上羟基, 形成一个无定形的混合氧化物状态; 在600℃以上无定形态结晶为晶态氧化物混合物。异丙醇探针反应表明, 柱撑水滑石具有高于水滑石前驱体和相应杂多酸盐的催化活性, 且同时存在酸碱两类催化活性中心, 但酸中心明显较强。     

固体氩中一氧化氮的低温氧化

本文研究了在低温固体Ar中NO和O~2的反应。采用Ar作基质, 将NO和O~2分层沉积或混合沉积在低温基板上, 通过逐渐升温来控制扩散速率, 在温度10K-35K范围内, 从样品付里叶变换红外光谱的变化, 首次观察了NO和O~2反应中间体的生成和转化, 由此给出了反应机理, 即NO在Ar基质中首先发生扩散和聚合, 生成cis-(NO)~2, 随后与氧反应生成asym-N~2O~3和iso-N~2O~4, 而asym-N~2O~3进一步氧化生成N~2O~4(D~2~h)。     

非晶态金属合金作催化材料的研究I:N-P非晶态合金对苯乙烯加氢活性的研究

本文用X射线光电子能谱(XPS), X射线衍射(XRD)和连续微型反应器等方法研究了以骤冷法制备的Ni-P非晶态催化剂的表面结构和加氢活性。结果表明, 非晶态Ni-P对于苯乙烯催化加氢具有很高的反应活性, 优于晶态Ni-P, 更优于Ni片, 催化剂表面不同的预处理条件, 对反应活性影响很大。XPS结果表明, 在适当的预处理条件下, 非晶态Ni-P被部分氧化;随着氧化态被还原, 反应活性逐渐下降。     

涡流发生器强化暖气片散热特性的数值研究

本文提出了一种基于纵向涡流发生器强化换热结构的暖气片散热器,并对其散热性能进行了数值模拟研究,着重分析了暖气片附近区域的温度场与速度场,基于场协同原理对其强化传热机理进行了解释,同时讨论了三角翼纵向涡流发生器的攻角与布置间距等关键参数对散热性能的影响.结果 表明,涡流发生器能显著增强散热,当三角翼纵向涡流发生器攻角为4...     

V-5Cr-5Ti合金弹性和力学性质的第一性原理研究

V-5Cr-5Ti合金作为核聚变堆第一包层的主要候选结构材料之一,但对其力学性质的理论研究相对较少.采用随机固溶体模型,利用第一性原理方法计算出V-5Cr-5Ti合金的弹性常数、体模量、剪切模量、杨氏模量、泊松比和柯西压力等,并与计算出的纯钒的相关数值进行对比,结果表明V-5Cr-5Ti合金具有良好的塑性和强度,但其塑性要略低于纯钒的.并对加入氧原子后的V-5Cr-5Ti合金进行了相关计算,通过对比计算结果发现,由于氧原子的加入,使V-5Cr-5Ti合金的塑性和强度都出现了不同程度的降低.最后对V-5Cr-5Ti合金和纯钒的理论强度进行了计算,并绘制出两者的应力-应变关系图,通过对比再次验证了上面的结论.